| 1 | Author | Jochen Eilermann, Martin Lietz | Requires cookie* |
| Title | Chemie polyfunktioneller Liganden, 60 [1] Über Käfigverbindungen mit den Heteroelementen Arsen und Selen Chemistry of Polyfunctional Ligands, 60 [1] On Cage Compounds with the Heteroelements Arsenic and Selenium  | ||
| Abstract | The reaction of l,l,l-tris(diiodoarsinomethyl)ethane, CH3C(CH2Asl2)3 (1) with NaAs(CeH5)2 in the molar ratio of 1:3 gives 4-methyl-l,2,6-triarsa-tricyclo[2,2,l,0 2 -6 ]-heptane, CH3C(CH2As)3 (2). The previously synthesized CH3C(CH2AsS)3 (4) can be de-sulphurated with triphenylphosphine to yield also 2. The reaction of 1 with NaSeH gives the new cage compound 6-methyl-l,3,4-triarsa-2,8-diselena-tricyclo[3,3,l,0 3 > 4 ]-nonane, CH3C(CH2As)3Se2 (5). | ||
| Reference | Z. Naturforsch. 35b, 1514—1517 (1980); eingegangen am 5. August 1980 | ||
| Published | 1980 | ||
| Keywords | Hetero Cage Compounds, Synthesis, Vibrational Spectra, Mass Spectra, 1 H NMR Spectra | ||
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