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Title | H-NM R-und IR-spektroskopische Untersuchungen zur Konformation von Hydroxy - methyl-Substituenten in 2.3-Stellung an Hexachlorbicycloheptenen ![]() | ||
Abstract | -an d IR -S pectroscopic C onform ational Studies on H ydro x y m eth y l S u b stitu en ts in th e 2,3 P ositions of H exachlorobicycloheptenes H e l l m u t S i n g e r *, I n g o l f S c h u p h a n ** u n d K a r l h e i n z B a l l s c h m i t e r Mono Hexachloro-bicycloheptenes and heptadienes with hydroxym ethyl-substituents in the 2 and 3 position show non-equivalence of the methylene protons in their NMR spectra. This is caused both by hindered rotation and the asymmetry of the molecules. For some molecules the spectroscopic data allow conclusions to be made concerning the con formation of the substituents. | ||
Reference | (Z. Naturforsch. 30b, 373—377 [1975]; eingegangen am 9. Dezember 1974) | ||
Published | 1975 | ||
Keywords | -hydroxymethyl-bicycloheptenes, Bis-hydroxymethyl-bicycloheptenes, Heptadienes, Hindered Rotation, Hydrogen Bonding | ||
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