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1989 (1)
1Author    Tetraphenylphosphonium Hexachlorodizincate, Hexachlorodicadmate, JörgH. Ubertus, Wilhelm, Ulrich MüllerRequires cookie*
 Title    Tetraphenylphosphonium-hexachlorodizinkat und -hexachlorodicadmat, (PPh4)2Zn2CI6 und (PPh4)2Cd2Cl6  
 Abstract    The title com pounds were obtained by the reactions of PPh4Cl. HC1 and ZnS or CdS in C H 2C12. Their crystal structures were determ ined by X-ray diffraction. (PPh4),Z n,C l6: a = 973.6(1), b = 982.6(2), c = 1296.7(3) pm, a = 107.93(2), ß = 94.50(2), y = 100.91(2)°, R = 0.036 for 2237 unique observed reflexions. (PPh4)2Cd2Cl6: a = 977.1(2), b = 997.5(3). c = 1306.6(3) pm. a = 108.81(2), ß = 94.18(2), y = 100.24(2)°, R = 0.050 for 1921 reflexions. Both com pounds are isotypic in the triclinic space group P I and consist of PPh4 ions and dimeric, centrosymm etric M2Clg-ions in which the tetrahedrally coordinated metal atoms are linked via chloro bridges. Synthese von (PPh4)2Zn2Cl6 und (PPh4)2Cd2CI6 
  Reference    Z. Naturforsch. 44b, 1037—1040 (1989); eingegangen am 26. April 1989 
  Published    1989 
  Keywords    H exachlorodizincate, H exachlorodicadm ate, Synthesis, Crystal Structure 
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 TEI-XML for    default:Reihe_B/44/ZNB-1989-44b-1037.pdf 
 Identifier    ZNB-1989-44b-1037 
 Volume    44