| | 1 | Author
| Tetraphenylphosphonium Hexachlorodizincate, Hexachlorodicadmate, JörgH. Ubertus, Wilhelm, Ulrich Müller | Requires cookie* | | | Title
| Tetraphenylphosphonium-hexachlorodizinkat und -hexachlorodicadmat, (PPh4)2Zn2CI6 und (PPh4)2Cd2Cl6  | | | | Abstract
| The title com pounds were obtained by the reactions of PPh4Cl. HC1 and ZnS or CdS in C H 2C12. Their crystal structures were determ ined by X-ray diffraction. (PPh4),Z n,C l6: a = 973.6(1), b = 982.6(2), c = 1296.7(3) pm, a = 107.93(2), ß = 94.50(2), y = 100.91(2)°, R = 0.036 for 2237 unique observed reflexions. (PPh4)2Cd2Cl6: a = 977.1(2), b = 997.5(3). c = 1306.6(3) pm. a = 108.81(2), ß = 94.18(2), y = 100.24(2)°, R = 0.050 for 1921 reflexions. Both com pounds are isotypic in the triclinic space group P I and consist of PPh4 ions and dimeric, centrosymm etric M2Clg-ions in which the tetrahedrally coordinated metal atoms are linked via chloro bridges. Synthese von (PPh4)2Zn2Cl6 und (PPh4)2Cd2CI6 | | | |
Reference
| Z. Naturforsch. 44b, 1037—1040 (1989); eingegangen am 26. April 1989 | | | |
Published
| 1989 | | | |
Keywords
| H exachlorodizincate, H exachlorodicadm ate, Synthesis, Crystal Structure | | | |
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| default:Reihe_B/44/ZNB-1989-44b-1037.pdf | | | | Identifier
| ZNB-1989-44b-1037 | | | | Volume
| 44 | |
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