| 3 | Author
| NazmiA. Kassab, AbdulHammid Harhash, SaidA. Elbahaii | Requires cookie* | | Title
| Cleavage Reactions of Oxazolin-5-ones Reactions with 4-Substituted-2-aryl-2-oxazolin-5-ones  | | | Abstract
| The oxazoline ring in 4-arylazo-2-aryl-2-oxazolin-5-ones (1) is converted to triazolyl-carbonyl amino acids 2, 4 and 6 by the nucleophiles glycine, anthranilic and p-aminobenzoic acids, respectively. The arylidene derivatives 3 of 2-triazolyl-2-oxazolin-5-one were obtained. Triazolylbenzoxazinones 5, were obtained by the ring closure of the amino acid 4. Grignard's reagent effected ring cleavage of the oxazolinone ring in 4-cinnamylidene-2-aryl-2-oxazolin-5-ones yielding the carbinols 8, the latter cyclizes either in acidic or alkaline medium to afford either benzotropilidenes or oxazolines, respectively. | | |
Reference
| Z. Naturforsch. 33b, 1145—49 (1978); received April 7/June 22 1978 | | |
Published
| 1978 | | |
Keywords
| Ring Cleavage, Triazolylcarbonyl Amino Acids, Nucleophilic Substitution, Grignard's Reaction, Ring Closure | | |
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| default:Reihe_B/33/ZNB-1978-33b-1145.pdf | | | Identifier
| ZNB-1978-33b-1145 | | | Volume
| 33 | |
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