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'Glycosyl Cyanides' in keywords Facet   Publication Year 1998  [X]
Facet   section ZfN Section B  [X]
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1Author    Wieslawa KudelskaRequires cookie*
 Title    Synthesis of Glycosyl Cyanides by the Reaction of 1-5-Phosphorothioates of Carbohydrates with Trimethylsilyl Cyanide  
 Abstract    A new procedure is described for the synthesis of a,/?-glycosyl cyanides by the reaction of per-O-benzylated S-a-D-glycopyranosyl phosphorothioates with trimethylsilyl cyanide in the presence of Lewis acid. Starting S-glycosyl phosphorothioates are prepared, directly, from O-benzyl protected reducing D-hexopyranoses (gluco-, galacto-, manno-) and alkylammonium salt of phosphorothioic acid under Lewis acid catalysis. 
  Reference    Z. Naturforsch. 53b, 1277—1280 (1998); received July 23 1998 
  Published    1998 
  Keywords    S-Glycosylphosphorothioates, Glycosyl Cyanides, Synthesis 
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 TEI-XML for    default:Reihe_B/53/ZNB-1998-53b-1277.pdf 
 Identifier    ZNB-1998-53b-1277 
 Volume    53