| | 1 | Author
| J. Nolte, J. Grußdorf, F. Temps, H. Gg, Wagner | Requires cookie* | | | Title
| Kinetics of the Reaction HOCO + 0 2 in the Gas Phase  | | | | Abstract
| Using the discharge flow method, the kinetics of the gas phase reaction HOCO + 0 2 products (1) was investigated at room temperature and pressures around p « 2.0 mbar with Far Infrared Laser Magnetic Resonance (FIR-LMR) detection of HOCO, H0 2 , and OH. From the measured concen-tration-versus-time decay profiles of HOCO in the absence and presence of a large excess of 0 2 , the overall rate constant of the reaction was found to be k, (296 K) = (9.9 ±1.5) • 10 11 cm 3 /mol • s. The main reaction channel, which leads to production of H0 2 + C0 2 , could be established. | | | |
Reference
| Z. Naturforsch. 48a, 1234—1238 (1993); received November 3 1993 | | | |
Published
| 1993 | | | |
Keywords
| Chemical kinetics, Gases, Radicals, Spectroscopy, Laser Magnetic Resonance | | | |
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