| | 1 | Author
| H. Schmidbaur, R. Nowak, B. Huber, G. Müller | Requires cookie* | | | Title
| Synthese  | | | | Abstract
| und Kristallstruktur von [(C 6 Et 6)(C 6 H 5 Me)GaGaCI 4 ] 1/2 (C 6 Et 6): Ein gemischter Bis(i/ 6 -aren)gallium(I)-Komplex Synthesis and Crystal Structure of [(C 6 Et 6)(C 6 H 5 Me)GaGaCl4] • 1/2 (C 6 Et 6): A Mixed Bis(^ 6 -arene)gallium(I) Complex Crystals obtained from solutions of hexaethylbenzene and anhydrous Ga[GaCl 4 ] in toluene on cooling have the stoichiometry [(C 6 Et 6)(C 6 H 5 Me)GaGaCl 4 ] • 1/2 C 6 Et 6 . a = 9.760(1), b = 21.447(2), c = 17.754(2) A. ß = 95.47(1)°; monoclinic. space group P2,/n. Z = 4. Each Ga(I) center is ?/ 6 -bonded to one molecule of hexaethylbenzene and to one molecule of toluene. The two rings form an angle of 38,8°. The remaining crystal hexaethylbenzene is situated between two complex units, which are related by an inversion center located in the center of the ring. | | | |
Reference
| Z. Naturforsch. 43b, 1447—1452 (1988); eingegangen am 27. Juli 1988 | | | |
Published
| 1988 | | | |
Keywords
| Gallium(I) Arene Complex, Hexaethylbenzene, Crystal Structure | | | |
Similar Items
| Find | | | DEBUG INFO
| | | | | TEI-XML for
| default:Reihe_B/43/ZNB-1988-43b-1447.pdf | | | | Identifier
| ZNB-1988-43b-1447 | | | | Volume
| 43 | |
|
