| 1 | Author | Horst Kunkely, Arnd Vogler | Requires cookie* |
| Title | Photochemical Reductive Elimination of Nitrogen from Triazidogallium(III). Generation of Luminescent Gallium(I)  | ||
| Abstract | The irradiation of Ga(N3)3 in CH3CN leads to a reductive elimination of nitrogen according to the equation Gam(N3)3 —► Ga*N3 + 3N2 (0 = 0.002 at Ain = 254 nm). Ga+ in CH3CN is characterized by its absorption (Amax = 298 nm) and emission (Amax = 475 nm) spectrum. | ||
| Reference | Z. Naturforsch. 53b, 1180—1182 (1998); received July 9 1998 | ||
| Published | 1998 | ||
| Keywords | Photochemistry, Charge Transfer, Gallium Complexes, Azide Complexes | ||
| Similar Items | Find | ||
