| | 1 | Author
| Christoph Kümmel, Anton Meller, Mathias Noltemeyer | Requires cookie* | | | Title
| Intramolekular-stabilisierte Organogallium-und -indiumhalogenide. Ein erstes neutrales Indiumhydrid Intramolecularly Stabilized Organogallium-and -indium Halides. A First Neutral Indium Hydride  | | | | Abstract
| The intramolecularly coordinating 2-(dimethylaminomethyl)phenyl-(X) and 4-terr-butyl-2,6-bis(dimethylaminomethyl)phenyl-(Y) ligands were employed in the preparation of the gallium and indium halides: X2InI (B), XInI2 (1), X2InBr (2), XInBr2 (3), XIn(Et)I (4), XGaI2 (6) and YInI2 (7). The first neutral indium hydride X2InH (5) was made in situ from LiInH4 and 2. Z2InCl (8) (Z = 2-pyridyl-bis(trimethylsilyl)methyl), and X3Ga (C) were also synthesized. The compounds are characterized by N. M. R. ('H, 13C, 29Si and for 6 71Ga) and mass spectrometry and elemental analyses or peak matching M. S.. N. M. R.-data are discussed as well as the X-ray structure analyses provided for B, 2, 4, 5, 7 and 8. | | | |
Reference
| Z. Naturforsch. 51b, 209—219 (1996); eingegangen am 13. Juli 1995 | | | |
Published
| 1996 | | | |
Keywords
| Gallium Halides, Indium Halides, Gallium Aryls, Indium Aryls, Aryl Indium Hydride | | | |
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| default:Reihe_B/51/ZNB-1996-51b-0209.pdf | | | | Identifier
| ZNB-1996-51b-0209 | | | | Volume
| 51 | |
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