| | 1 | Author
| G. Ar Zeller, Ette Schier, B. Ert, Schm Idbaur | Requires cookie* | | | Title
| The Crystal Structure of [Bis(tri-'butyl-phosphine)gold(I)] Chloride  | | | | Abstract
| The title compound is available from the reaction of labile gold(I) chloride com plexes and an excess of the ligand ('Bu3P), or from the N aBH 4 reduction of ('Bu3P)AuCl. It forms dark red cubic crystals, [a = 14.297(1) A at -5 6 °C, space group P2j3, Z = 4], with isolated chloride anions and [('Bu3P)2Au]+ cations of C3 symmetry, with linear two-coordinate gold centers. | | | |
Reference
| Z. Naturforsch. 49b, 1243—1246 (1994); received June 8 1994 | | | |
Published
| 1994 | | | |
Keywords
| G old(I) Complexes, Phosphine Complexes, Gold(I) Coordination, Steric Effect, Crystal Structure | | | |
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| default:Reihe_B/49/ZNB-1994-49b-1243.pdf | | | | Identifier
| ZNB-1994-49b-1243 | | | | Volume
| 49 | |
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