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'Fumaronitrile Complexes' in keywords
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1994 (1)
1Author    İzzetA. Mour, Saim Ozkar, CorneliusG. KreiterRequires cookie*
 Title    Synthesis and Spectroscopic Studies of Pentacarbonylfumaronitrile-chromium(O), -molybdenum(O), and -tungsten(O)  
 Abstract    Photolysis of hexacarbonyl-chromium(O), -molybdenum(O), and -tungsten(O) in presence of fumaronitrile yields at room tem perature pentacarbonyl-fumaronitrile-chromium(O) (1), -molybdenum(O) (2), and -tungsten(O) (3). The complexes were purified by crystallization and characterized by IR and 13C-NM R spectroscopy. The fumaronitrile ligand is bonded to the M (CO)5 moiety by one nitrile nitrogen atom rather than by the carbon-carbon double bond. In toluene 2 dissociates into fumaronitrile and pentacarbonyl-molybdenum(O), which is stabi­ lized by the solvent. Fumaronitrile and solvated pentacarbonyl-molybdenum(O) exist in solu­ tion together with 2 in an equilibrium which lies in favour of the former species. 
  Reference    Z. Naturforsch. 49b, 1059—1062 (1994); eingegangen am 13. April 1994 
  Published    1994 
  Keywords    Chromium, Molybdenum, Tungsten, Carbonyl, Fumaronitrile Complexes 
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 TEI-XML for    default:Reihe_B/49/ZNB-1994-49b-1059.pdf 
 Identifier    ZNB-1994-49b-1059 
 Volume    49