| | 1 | Author
| G. Waidmann, M. Jansen | Requires cookie* | | | Title
| Synthese und Charakterisierung des Fulleren-Kokristallisats C60*SiH(C6H5)3 Synthesis and Characterisation of the Fullerene Co-Crystal C60*SiH(C6H5)3  | | | | Abstract
| A new fullerene co-crystal C60*SiH(C6H5)3 has been synthesized by crystallisation from a melt of SiH(C6H5)3 and C60 in sealed duran tubes at 80°C. X-ray investigations led to triclinic symmetry, space group P i, a = 10.086(1),/? = 14.431(2), c = 14.911(2) Ä, a = 79.13(1), ß = 74.943(9), 7 = 88.33(1)°, V = 2058.0(4) A 3, Z = 2. The crystal structure consists of isolated fullerene and silane molecules. At -80°C, C60 is still rotationally disordered. Temperature dependent Guinier powder diagrams do not show any phase transformation between 25 and -165°C. The compound is stable in air. | | | |
Reference
| Z. Naturforsch. 53b, 161—164 (1998); eingegangen am 14. November 1997 | | | |
Published
| 1998 | | | |
Keywords
| Fullerene C60, Synthesis, Crystal Structure | | | |
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| default:Reihe_B/53/ZNB-1998-53b-0161.pdf | | | | Identifier
| ZNB-1998-53b-0161 | | | | Volume
| 53 | |
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