| | 1 | Author
| N. Orbert Auner, Erika Penzenstadler | Requires cookie* | | | Title
| Silaheterocyclen, XIII Erzeugung und Cycloadditionsverhalten von l,3-Diaza-2,4-disila-unj 1.3-Disilacyclobutanen mit exocyclischer SiC-Doppelbindung Silaheterocycles, XIII Form ation and Cycloaddition Reactions of l,3-Diaza-2,4-disila-and 1.3-Disilacyclobutanes Containing an Exocyclic SiC Double Bond  | | | |
Reference
| Z. Naturforsch. 47b, 217 (1992); eingegangen am 16. Juli/19. August 1991 | | | |
Published
| 1992 | | | |
Keywords
| Silaheterocycles, Synthesis o f l, 3-Diaza-2, 4-disilacyclobutane, Form ation o f Silenes, Cycloaddition Reactions | | | |
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| default:Reihe_B/47/ZNB-1992-47b-0217.pdf | | | | Identifier
| ZNB-1992-47b-0217 | | | | Volume
| 47 | |
| 2 | Author
| N. Orbert Auner, Erika Penzenstadler, Eberhardt Herdtweck | Requires cookie* | | | Title
| Silaheterocyclen, XX Aminosubstituierte Vinylchlorsilane und Silaethene: Bausteine zur Synthese von l,3-Diaza-2-silacyclopentanen [1] Silaheterocycles, XX Am inosubstituted Vinylchlorosilanes and Silenes: Building Blocks for the Synthesis of l,3-Diaza-2-silacyclopentanes [1] | | | | Abstract
| The amino-substituted vinylchlorosilanes 4 -7 are synthesized from N ,N ,N '-trim ethyl-ethylenediamine (8 a) or tris(trimethylsilyl)ethylenediamine (8 b), LiBu" and organodichloro-vinylsilanes. 5 eliminates trimethylchlorosilane when distilled and yields 1,3-diaza-2-silacyclopentane 9, whereas the com pounds 6 and 7 show a great tendency to oligomerize. The reaction o f 4 with LiBu1 gives a neopentylsilene intermediate 10 a which can be trapped by isoprene or 1,3-butadiene yielding small amounts o f the Diels-Alder products 11 and 12, re spectively. The main reaction pathway for 10 a is rearrangement with migration o f a M e3Si-group from nitrogen to the silene's carbon atom and a new N —Si bond formation to give the diazasilacyclopentane 10 which has been characterized by X-ray diffraction analysis. This in tramolecular rearrangement appears to involve a pentacoordinated silene Si-atom. N o dimer-isation o f 10a to a disilacyclobutane is observed. The introduction o f a second Si-tris(tri-methylsilyl)ethylenediamine substituent at the SiC frame work does not result in silene stabili sation: there is no evidence for Si-hexacoordination in silene 15 nor in the [4+2] cyclo-addition product with isoprene (14). | | | |
Reference
| Z. Naturforsch. 47b, 1377—1385 (1992); eingegangen am 6. Mai 1992 | | | |
Published
| 1992 | | | |
Keywords
| Silaheterocycles, Synthesis, Form ation o f Silenes, Cycloaddition Reactions, Highly C oordinated Silicon | | | |
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| default:Reihe_B/47/ZNB-1992-47b-1377.pdf | | | | Identifier
| ZNB-1992-47b-1377 | | | | Volume
| 47 | |
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