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1987 (1)
1Author    Hansjörg Grützm, H. Erbert, W. Roesky, Mathias Noltem, GeorgeM. SheldrickRequires cookie*
 Title    Substitutionsreaktionen am N-[l-Chlor-2,2,2-trifluor-l-(trifluormethyl)ethyl]-dimethyIformamidin Substitution Reactions with N -[l-Chloro-2,2,2-trifluoro-l-(trifluorom ethyl)ethyl]-dim ethylform am idine  
 Abstract    It is difficult to achieve nucleophilic attack on a carbon atom bonded on two trifluoromethyl groups. However, N-[l-chloro-2,2,2-trifluoro-l-(trifluoromethyl)ethyl]-dimethylformamidine (1) reacts readily with H20 , MeOH, EtSH and P(OM e)3 even under mild conditions to form products 2, 3, 4 and 5. The reaction between 1 and Ph2PH is complex but leads in nearly quantitative yield to N-[2,2,2-trifluoro-l-(trifluoromethyl)ethyl]-dimethylformamidinium chloride 6 which has been characterized by an X-ray structure analysis. A reaction mechanism is proposed. 
  Reference    Z. Naturforsch. 42b, 1245—1248 (1987); eingegangen am 5. Mai/27. Juni 1987 
  Published    1987 
  Keywords    MS Spectra, Fluoroorganic Compounds, NMR Spectra 
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 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-1245.pdf 
 Identifier    ZNB-1987-42b-1245 
 Volume    42