| | 1 | Author
| Bernhard Ciommer, Helmut Schwarz | Requires cookie* | | | Title
| Zur intermediären Existenz von Ethylenfluoronium-Ionen in der Gasphase On the Intermediary Existence of Gaseous Ethylen Fluoronium Ions  | | | | Abstract
| The long-sought ethylen fluoronium ion (2) is generated as an intermediate in the dissociative ionization of l-fluoro-2-(^-methyl)phenoxy ethane (4). However, prior to collisionally induced dissociation 2 undergoes ring-opening, associated with hydrogen migration, to form 1-fluoroethyl cation (3). Other decomposition pathways of the molecular ions of 4 involve (i) direct formation of 3 via a combination of C-O-cleavage (loss of ArO -) and [1,2] hydrogen migration (18%) and (ii) complete positional loss of the a-and ß-methylene hydrogen atoms (34%). The remaining 48% of the molecular ions of 4 dissociate via anchimeric assistance of the fluorine in the elimination of ArO -, thus giving rise to the formation of 2. | | | |
Reference
| Z. Naturforsch. 38b, 635—638 (1983); eingegangen am 23. Dezember 1982 | | | |
Published
| 1983 | | | |
Keywords
| Fluoronium Ions, Neighbouring Group Participation, Gaseous Ions, Collisional Activation, Mass Spectrometry | | | |
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| default:Reihe_B/38/ZNB-1983-38b-0635.pdf | | | | Identifier
| ZNB-1983-38b-0635 | | | | Volume
| 38 | |
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