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'Fluoro C hloro Platinates IV' in keywords
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1989 (1)
1Author    P. E. Rlhöfer, W. PreetzRequires cookie*
 Title    Darstellung und Schwingungsspektren der 35CI/37Cl-markierten Fluoro-Chloro-Platinate(IV) Preparation and Vibrational Spectra of 35C1/ Cl Labelled Fluoro-Chloro-Platinates(IV)  
 Abstract    A ll com ponents of the two series Cs2[PtF"35Cl6_"] and Cs2[PtF"37ClA_"], including the pairs of geom etric isomers for n = 2 ,3 , 4, have been prepared and isolated by ion exchange chrom atogra­ phy on D E A E cellulose. The highly resolved low temperature (80 K) IR and Raman spectra of the pure isotopom ers show distinctive isotopic shifts for different vibrational m odes up to 10 cm -1 . The excellent agreem ent o f the observed values with Teller-R edlich calculations verifies the assignm ent of all stretching and especially o f the narrow deform ation bands. For trans -com plexes containing C l—P t— Cl axes, the lowered of mutual exclusion. 
  Reference    Z. Naturforsch. 44b, 619 (1989); eingegangen am 8. Februar 1989 
  Published    1989 
  Keywords    Fluoro-C hloro-Platinates(IV ), Isotopom ers, Teller-Redlich Calculation, IR Spectra, Raman Spectra 
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 TEI-XML for    default:Reihe_B/44/ZNB-1989-44b-0619.pdf 
 Identifier    ZNB-1989-44b-0619 
 Volume    44