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1989 (1)
1Author    R. Oland Boese, D. Ieter Bläser, M. Bolatiana Andrianarison, Uwe KlingebielRequires cookie*
 Title    Lithio-di-terf-butylfluorsilyl-te/t-butylphosphan — Kristallstruktur und Reaktionen Lithio-di-terf-butylfluorosilyl-ferr-butylphosphane — Crystal Structure and Reactions  
 Abstract    Di-/er/-butylfluorosilyl-fe/7-butylphosphane (1) reacts with «-C 4H gLi to give the lithium salt (C M e3)2S iF —PLi(TFIF)3CM e3 (2) and butane. The crystal structure o f 2 has been determ ined. Fluorosilylphosphanes of the type (C M e3)2SiFP(R)C M e3 [R = SiM e3 (5), SiCl2Me (6). SiCl3 (7), SiF2CA H 5 (8), B F N (SiM e3)2 (9), SiClM eP(CM e3)SiF(CM e3)2 (10)] are obtained in the reaction of 2 with halogenosilanes and -borane. 6 and 7 undergo rearrangement via chloro-fluoro exchange reaction to give (C M e3)2S iC l-P (S iC lR F)C M e3 [R = Cl (11), Me (12)]. 
  Reference    Z. Naturforsch. 44b, 265 (1989); eingegangen am 7. N ovem ber 1988 
  Published    1989 
  Keywords    F luorosilylphosphanes, Lithium Salt, Crystal Structure Phosphasilene, Fluoro-C hloro Exchange 
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 TEI-XML for    default:Reihe_B/44/ZNB-1989-44b-0265.pdf 
 Identifier    ZNB-1989-44b-0265 
 Volume    44