| | 1 | Author
| J. Dautel, S. Abele, W. Schwarz | Requires cookie* | | | Title
| Synthese von 2,2-DiphenylethyI-substituierten Silanen -Molekülstruktur von Trichlor-2,2-diphenylethylsilan Syntheses of 2,2-Diphenylethyl-Substituted Silanes -Molecular Structure of Trichloro-2,2-diphenylethylsilane  | | | | Abstract
| Hydrosilylation of 1,1-diphenylethylene with trichlorosilane leads in high yields to trichloro-2.2-diphenylethylsilane (1), which was investigated spectroscopically as well as by X-ray structure determination. The compound crystallizes monoclinically in the acentric space group Cc {a = 1002.4, b = 1573.8, c = 979.7 pm, ß = 106.27°, Z = 4}; the bonding parameters show no special features. By fluorination with zinc(II) fluoride in diethylether and by reduction with "Red-Al" in toluene, the corresponding SiF3 (2) and SiH3 derivatives (3) are received, respectively. | | | |
Reference
| Z. Naturforsch. 52b, 778—784 (1997); eingegangen am 13. März 1997 | | | |
Published
| 1997 | | | |
Keywords
| 22-Diphenylethyl-Substituted Silanes, Fluorination, X-Ray | | | |
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| default:Reihe_B/52/ZNB-1997-52b-0778.pdf | | | | Identifier
| ZNB-1997-52b-0778 | | | | Volume
| 52 | |
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