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'Fluorination' in keywords Facet   section ZfN Section B:Volume 052  [X]
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1997 (1)
1Author    J. Dautel, S. Abele, W. SchwarzRequires cookie*
 Title    Synthese von 2,2-DiphenylethyI-substituierten Silanen -Molekülstruktur von Trichlor-2,2-diphenylethylsilan Syntheses of 2,2-Diphenylethyl-Substituted Silanes -Molecular Structure of Trichloro-2,2-diphenylethylsilane  
 Abstract    Hydrosilylation of 1,1-diphenylethylene with trichlorosilane leads in high yields to trichloro-2.2-diphenylethylsilane (1), which was investigated spectroscopically as well as by X-ray structure determination. The compound crystallizes monoclinically in the acentric space group Cc {a = 1002.4, b = 1573.8, c = 979.7 pm, ß = 106.27°, Z = 4}; the bonding parameters show no special features. By fluorination with zinc(II) fluoride in diethylether and by reduction with "Red-Al" in toluene, the corresponding SiF3 (2) and SiH3 derivatives (3) are received, respectively. 
  Reference    Z. Naturforsch. 52b, 778—784 (1997); eingegangen am 13. März 1997 
  Published    1997 
  Keywords    22-Diphenylethyl-Substituted Silanes, Fluorination, X-Ray 
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 TEI-XML for    default:Reihe_B/52/ZNB-1997-52b-0778.pdf 
 Identifier    ZNB-1997-52b-0778 
 Volume    52