| | 1 | Author
| Jochen Jander, HansOtto Mayer | Requires cookie* | | | Title
| Fluorination of Ammine Complexes of Platinum(IV) in Aqueous Solution  | | | | Abstract
| Unlike chlorination fluorination of ammine complexes of platinum(IV) in aqueous solution does not lead to haloamido complexes. Instead, the triammine complexes [Pt(NH3)3Cl3]Cl and [Pt(NH3)3(NCl2)2Cl]Cl yield no definite main product, and the tetrammine and pentammine complexes trans-[Pt(NH3)4C12]C12, [Pt(NH3)4(NCl2)Cl]Cl2, [Pt(NH3)5Cl]Cl3, and [Pt(NH3)5(OH)]Cl3 form the sparingly soluble complex trans -[Pt (NH3)4C12] (H2F3)2 • 2 H-20 as the main product. | | | |
Reference
| Z. Naturforsch. 33b, 1561—1562 (1978); eingegangen am 1. September 1978 | | | |
Published
| 1978 | | | |
Keywords
| Fluorination, Ammine Complexes, Platinum(IV) | | | |
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| | | | | TEI-XML for
| default:Reihe_B/33/ZNB-1978-33b-1561_n.pdf | | | | Identifier
| ZNB-1978-33b-1561_n | | | | Volume
| 33 | |
| 2 | Author
| J. Dautel, S. Abele, W. Schwarz | Requires cookie* | | | Title
| Synthese von 2,2-DiphenylethyI-substituierten Silanen -Molekülstruktur von Trichlor-2,2-diphenylethylsilan Syntheses of 2,2-Diphenylethyl-Substituted Silanes -Molecular Structure of Trichloro-2,2-diphenylethylsilane | | | | Abstract
| Hydrosilylation of 1,1-diphenylethylene with trichlorosilane leads in high yields to trichloro-2.2-diphenylethylsilane (1), which was investigated spectroscopically as well as by X-ray structure determination. The compound crystallizes monoclinically in the acentric space group Cc {a = 1002.4, b = 1573.8, c = 979.7 pm, ß = 106.27°, Z = 4}; the bonding parameters show no special features. By fluorination with zinc(II) fluoride in diethylether and by reduction with "Red-Al" in toluene, the corresponding SiF3 (2) and SiH3 derivatives (3) are received, respectively. | | | |
Reference
| Z. Naturforsch. 52b, 778—784 (1997); eingegangen am 13. März 1997 | | | |
Published
| 1997 | | | |
Keywords
| 22-Diphenylethyl-Substituted Silanes, Fluorination, X-Ray | | | |
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| default:Reihe_B/52/ZNB-1997-52b-0778.pdf | | | | Identifier
| ZNB-1997-52b-0778 | | | | Volume
| 52 | |
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