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'Fluorination' in keywords Facet   section ZfN Section B  [X]
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1997 (1)
1978 (1)
1Author    Jochen Jander, HansOtto MayerRequires cookie*
 Title    Fluorination of Ammine Complexes of Platinum(IV) in Aqueous Solution  
 Abstract    Unlike chlorination fluorination of ammine complexes of platinum(IV) in aqueous solution does not lead to haloamido complexes. Instead, the triammine complexes [Pt(NH3)3Cl3]Cl and [Pt(NH3)3(NCl2)2Cl]Cl yield no definite main product, and the tetrammine and pentammine complexes trans-[Pt(NH3)4C12]C12, [Pt(NH3)4(NCl2)Cl]Cl2, [Pt(NH3)5Cl]Cl3, and [Pt(NH3)5(OH)]Cl3 form the sparingly soluble complex trans -[Pt (NH3)4C12] (H2F3)2 • 2 H-20 as the main product. 
  Reference    Z. Naturforsch. 33b, 1561—1562 (1978); eingegangen am 1. September 1978 
  Published    1978 
  Keywords    Fluorination, Ammine Complexes, Platinum(IV) 
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 TEI-XML for    default:Reihe_B/33/ZNB-1978-33b-1561_n.pdf 
 Identifier    ZNB-1978-33b-1561_n 
 Volume    33 
2Author    J. Dautel, S. Abele, W. SchwarzRequires cookie*
 Title    Synthese von 2,2-DiphenylethyI-substituierten Silanen -Molekülstruktur von Trichlor-2,2-diphenylethylsilan Syntheses of 2,2-Diphenylethyl-Substituted Silanes -Molecular Structure of Trichloro-2,2-diphenylethylsilane  
 Abstract    Hydrosilylation of 1,1-diphenylethylene with trichlorosilane leads in high yields to trichloro-2.2-diphenylethylsilane (1), which was investigated spectroscopically as well as by X-ray structure determination. The compound crystallizes monoclinically in the acentric space group Cc {a = 1002.4, b = 1573.8, c = 979.7 pm, ß = 106.27°, Z = 4}; the bonding parameters show no special features. By fluorination with zinc(II) fluoride in diethylether and by reduction with "Red-Al" in toluene, the corresponding SiF3 (2) and SiH3 derivatives (3) are received, respectively. 
  Reference    Z. Naturforsch. 52b, 778—784 (1997); eingegangen am 13. März 1997 
  Published    1997 
  Keywords    22-Diphenylethyl-Substituted Silanes, Fluorination, X-Ray 
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 TEI-XML for    default:Reihe_B/52/ZNB-1997-52b-0778.pdf 
 Identifier    ZNB-1997-52b-0778 
 Volume    52