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'Ferrocene Complexes' in keywords Facet   Publication Year 1995  [X]
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1Author    Oliver Seidelmann, Lothar Beyer, Rainer RichterRequires cookie*
 Title    N,N-Disubstituierte N'-Ferrocenoylthioharnstoffe als zweizähnige Komplexliganden für Übergangsmetallionen. Kristallstruktur von Bis-(N,N-diethyl-N'-ferrocenoylthioureato)nickel(II) N,N-Disubstituted N'-Ferrocenoyl Thioureas as Bidentate Ligands for Transition Metal Ions. Crystal Structure of Bis-(N,N-diethyl-N'-ferrocenoylthioureato)nickel(II)  
 Abstract    N,N-diethyl-N'-ferrocenoyl-thiourea and N-(morpholino-thiocarbonyl)ferrocenecarboxylic amide have been prepared by the reaction of ferrocenoyl chloride with potassium thiocyanate and the respective amine in dry acetone. These bidentate ligands yield neutral heterometal-lic complexes with Ni(II), Cu(II), Mn(II) and Co(III). The dark brown air stable crystals of bis-(N,N-diethyl-N'-ferrocenoylthioureato)nickel(II) were characterized by X-ray structure de­ termination. Lattice dimensions: a = 1870.9(1), b = 1161.5(1), c = 1491.4(1) pm; space group Pca2!, Z = 4, R = 0.030 for 5707 observed reflections. 
  Reference    Z. Naturforsch. 50b, 1679—1684 (1995); eingegangen am 23. März 1995 
  Published    1995 
  Keywords    Ferrocene Complexes, Thiourea, Hetero Metal Complexes, Synthesis, Crystal Structure 
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 TEI-XML for    default:Reihe_B/50/ZNB-1995-50b-1679.pdf 
 Identifier    ZNB-1995-50b-1679 
 Volume    50