| | 1 | Author
| W.-D Griebler, D. Babel | Requires cookie* | | | Title
| Röntgenograpliische und magnetische Untersuchungen an perowskitverwandten Cyanoverbindungen CsM ,I M III (CN)6 X-Ray and Magnetic Studies of Perovskite-Related Cyano Compounds CsM II M TII (CN)6  | | | | Abstract
| The perovskite-related cyano compounds CsMnCr(CN)6 (Mn = Mn, Zn), CsZnFe(CN)6 and CsMnCo(CN)6 (Mn = Mn-Cu) are characterized by their IR active C N and Mm-CN stretching frequencies, their lattice constants and their magnetic suscept ibilities (4,2-295 K). Except for CsCuCo(CN)6, which is tetragonally distorted, all compounds crystallize cubically face-centered (with lattice constants in the range from 1020 to 1084 pm). The magnetic behaviour indicates low spin Mm and high spin Mn states, supporting the IR evidence for a strictly ordered Mm—CN—Mn arrangement. The compound CsMnCr(CN)6 is ferrimagnetic, with a Neel temperature of T>j = 90 K and an extrapolated spontaneous magnetization of a = 2,30 //B at 0 K. Superexchange interactions via the cyano bridges are considered responsible for the ferrimagnetism observed. | | | |
Reference
| Z. Naturforsch. 37b, 832—837 (1982); eingegangen am 5. März 1982 | | | |
Published
| 1982 | | | |
Keywords
| Cyano Perovskites, Lattice Constants, Magnetic Susceptibilities, Ferrimagnetism | | | |
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| default:Reihe_B/37/ZNB-1982-37b-0832.pdf | | | | Identifier
| ZNB-1982-37b-0832 | | | | Volume
| 37 | |
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