| | 1 | Author
| O. P. Pandey3, S. K. Sengupta3, B. P. Baranwal3, SarojK. Shuklab, Alpana Bhatt3 | Requires cookie* | | | Title
| Mono-and Bis(cyclopentadienyl)hafnium(IV) Derivatives with Higher Fatty Acids  | | | | Abstract
| The reactions o f Cp2HfCh with som e higher monocarboxylic acids having straight chains, caprylic (C8H16O2), lauric (C12H24O2), myristic (C14H28O2), palmitic (C16H32O2), stearic (C18H36O2), and behenic (C22H44O2) acid, have been studied in anhydrous tetrahydrofuran in 1:1 and 1:2 molar ratios, respectively. The reaction products isolated, o f types Cp2Hf(L)Cl, CpHf(L)2Cl (LH represents different carboxylic acids), have been characterised by conductivity and magnetic susceptibility measurements and spectral (infrared, electronic, *H NMR and 13C NMR) data. The bonding o f the carboxylato ligand in these complexes has been discussed and plausible structures have been established. | | | |
Reference
| Z. Naturforsch. 56b, 141—145 (2001); received April 28 2000 | | | |
Published
| 2001 | | | |
Keywords
| Cyclopentadienyl, Hafnium(IV), Fatty Acids | | | |
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| ZNB-2001-56b-0141 | | | | Volume
| 56 | |
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