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1992 (1)
1978 (1)
1976 (1)
1Author    Volker Müller, Gerlinde Frenzen, K. Urt Dehnicke, Dieter FenskeRequires cookie*
 Title    Synthese, FIR-Spektren und Kristallstrukturen der Pentaselenide K2Se5 und [Na(15-Krone-5)l2Se5 Syntheses, F IR Spectra, and Crystal Structures of the Pentaselenides K 2Se5 and [Na( 15-crown-5)]2Se5  
 Abstract    K2Se5 has been prepared by crystallization from a potassium polyselenide solution in D M F. In a similar way [Na(15-crown-5)]2Se5 can be prepared by crystallization from a sodium p oly­ selenide solution in D M F in the presence o f 15-crown-5. Both com pounds were characterized by FIR spectroscopy as well as by X-ray structure determinations. K2Se5: Space group P 2,2,2,, Z -4, 1659 observed independent reflections, R = 0.061. Lat­ tice dim ensions at -9 0 °C; a = 671.5(5), b = 694.9(5), c = 1776.4(9) pm. The com pound crys­ tallizes with the K2S5 type structure. [Na(15-crown-5)]2Se5: Space group P 1, Z = 2, 3026 observed indenpendent reflections, R = 0.140. Lattice dim ensions at -1 0 0 °C: a = 853.7(5), b = 1042.8(10), c = 2011.0(10) pm; a = 88.95(5)°, ß = 79.42(5)°, y = 66.15(5)°. The compound forms an ion triple, in which the sodium ions are coordinated by the five oxygen atoms o f the crown ether molecules as well as by the terminal selenium atom s o f the pentaselenide chain. The rather high R value is a result o f the disordered crown ether molecules. 
  Reference    Z. Naturforsch. 47b, 205 (1992); eingegangen am 23. August 1991 
  Published    1992 
  Keywords    Pentaselenides, Syntheses, FIR Spectra, Crystal Structure 
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 TEI-XML for    default:Reihe_B/47/ZNB-1992-47b-0205.pdf 
 Identifier    ZNB-1992-47b-0205 
 Volume    47 
2Author    Jochen Ellermann, HelmutA. LindnerRequires cookie*
 Title    Komplexchemie polyfunktioneller Liganden, XXXVIII  
 Abstract    Präparative und schwingungsspektroskopische Untersuchungen zum Reaktionsverhalten von Mn2(CO)10 gegenüber dem tritertiären Phosphin l.l.l-Tris(diphenylphosphinomethyl)äthan Complex Chemistry of Polyfunctional Ligands, XXXVIII 1 Preparative and Vibrational Spectroscopic Studies of the Reaction of Mn2(CO)10 with the Tritertiary Phosphine 1,1 ,l-Tris(diphenylphosphinomethyl)ethane Decacarbonyldimanganese reacts with the tritertiary phosphine l,l,l-tris(diphenylphos-phinomethyl)ethane (triphos) to give the ionic complex [Mn(CO)3triphos][Mn(CO)5]. Treatment of [Mn(CO)3triphos][Mn(CO)5] with Na[B(C6H5)4], HC104 and NH4PF6 yields the manganese (I) salts [Mn(CO)3triphos]Y (Y = B(C6H5)4, C104, PFe). The IR (2100-300 cm -1) and FIR spectra (350-200 cm -1) of all compounds are reported. Based on Ra-man polarization data the assignment of the v(CO) (Ai + E), <5(MnCO) (Ai + 2 E), j>(MnC) (Ai + E) and v(MnP) (Ai) modes was possible for the coordination polyhedra cts-Mn(CO)3P3 (point group C3v). The i'(MnP) (E) mode was unobserved due to its very low frequency. 
  Reference    (Z. Naturforsch. 31b, 1350—1355 [1976]; eingegangen am 23. Juli 1976) 
  Published    1976 
  Keywords    Manganesecarbonyl Derivatives, Tritertiary Phosphine, Raman Spectra, IR Spectra, FIR Spectra 
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 TEI-XML for    default:Reihe_B/31/ZNB-1976-31b-1350.pdf 
 Identifier    ZNB-1976-31b-1350 
 Volume    31 
3Author    Thomas Krück, Werner Thielmann, Christian SauerRequires cookie*
 Title    Metallkomplexe mit anionischen Liganden von Elementen der 4. Hauptgruppe, XI [1] Homogene Trichlorstannidometallat(O)-Komplexe der 6. und 8. Nebengruppe Metal Complexes with Anionic Ligands of Elements of the Main Group IV, XI [1] Homogenous Trichlorostannido Metalate(O) Complexes of the Transition Groups VI and VIII  
 Abstract    Various homogeneous metalate(O) complexes are synthesized with [SnCl3] -as a ligand. Complexes of the type [M(SnCl3)6] 6 -are prepared from [M(CO)3(SnCl3)3] 3 -(M = Cr, Mo, W) in nitromethane. [Fe(SnCl3)5] 5_ is formed by UV irradiation of [Fe(CO)4SnCl3]~ in aceto-nitrile. [M(SnCl3)4] 4-(M = Ni, Pd, Pt) anions are synthesized by thermal substitution reactions with Ni(CO)4, Pd(PF3)4, and Pt(PF3)4. All metalate(O) ions are isolated as salts with the [N(C2H5)4] + cation and characterized by IR spectra and 119m Sn-Mössbauer spectra as well as by analysis. 
  Reference    Z. Naturforsch. 33b, 1291—1295 (1978); eingegangen am 12. Juli 1978 
  Published    1978 
  Keywords    Synthesis, FIR Spectra, 119m Sn-Mössbauer Spectra, Metal Complexes, Anionic Ligands 
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 TEI-XML for    default:Reihe_B/33/ZNB-1978-33b-1291.pdf 
 Identifier    ZNB-1978-33b-1291 
 Volume    33