| | 1 | Author
| R. Oland Boese, D. Ieter Bläser, M. Bolatiana Andrianarison, Uwe Klingebiel | Requires cookie* | | | Title
| Lithio-di-terf-butylfluorsilyl-te/t-butylphosphan — Kristallstruktur und Reaktionen Lithio-di-terf-butylfluorosilyl-ferr-butylphosphane — Crystal Structure and Reactions  | | | | Abstract
| Di-/er/-butylfluorosilyl-fe/7-butylphosphane (1) reacts with «-C 4H gLi to give the lithium salt (C M e3)2S iF —PLi(TFIF)3CM e3 (2) and butane. The crystal structure o f 2 has been determ ined. Fluorosilylphosphanes of the type (C M e3)2SiFP(R)C M e3 [R = SiM e3 (5), SiCl2Me (6). SiCl3 (7), SiF2CA H 5 (8), B F N (SiM e3)2 (9), SiClM eP(CM e3)SiF(CM e3)2 (10)] are obtained in the reaction of 2 with halogenosilanes and -borane. 6 and 7 undergo rearrangement via chloro-fluoro exchange reaction to give (C M e3)2S iC l-P (S iC lR F)C M e3 [R = Cl (11), Me (12)]. | | | |
Reference
| Z. Naturforsch. 44b, 265 (1989); eingegangen am 7. N ovem ber 1988 | | | |
Published
| 1989 | | | |
Keywords
| F luorosilylphosphanes, Lithium Salt, Crystal Structure Phosphasilene, Fluoro-C hloro Exchange | | | |
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| default:Reihe_B/44/ZNB-1989-44b-0265.pdf | | | | Identifier
| ZNB-1989-44b-0265 | | | | Volume
| 44 | |
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