| | 1 | Author
| Wolfgang Hönle, Leonhard Walz, Hans Georg, Von Schnering | Requires cookie* | | | Title
| Bildung und Kristallstruktur von Ethylendiammonium-hydridotrioxophosphat(2 -) [^ N C F ^ C t^ N F y iP H C ^ p Form ation and Crystal Structure of Ethylenediammonium H ydridotrioxophosphate(2-) [HjNCFUCHoNI-ytPHO,]  | | | | Abstract
| Ethylenediammonium H yd ridotrioxophosphate(2-) [HjNCH-jCH-jNHjJITHO:,] is formed by slow oxidation o f white phosphorus by oxygen in ethylendiamine. It crystallizes in the space group Pbca with a = 1570.6(4) pm, b = 676.9(5) pm, c = 1267.8(4) pm and Z = 8 formula units in the unit cell. The structure is built from ethylenediammonium dications and tetra hedral phosphonate dianions, linked by O -H -N bonds (d(O--N) = 275.8 pm). The bond distances are d (P -O) = 151.8 pm, d (P -H) = 136.9 pm, d (N -C) = 148.3 pm and d (C -C) = 151.0 pm. | | | |
Reference
| Z. Naturforsch. 45b, 1251—1254 (1990); eingegangen am 13. Februar 1990 | | | |
Published
| 1990 | | | |
Keywords
| Ethylenediammonium H ydridotrioxophosphate(2-), Crystal Structure, Formation, Phosphonate Dianion, Ethylenediammonium Dication | | | |
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| default:Reihe_B/45/ZNB-1990-45b-1251.pdf | | | | Identifier
| ZNB-1990-45b-1251 | | | | Volume
| 45 | |
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