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'Ethylene Evolution' in keywords Facet   section ZfN Section C  [X]
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1999 (1)
1Author    Teruyuki Kobayashi3, Yumiko Sasakib, Tetsuya Akamatsub, Toshihiro Ishiic, YoshiakiO. Dac, Hideki Masuda3, Hisahiko Einaga3, Yuzo NishidaRequires cookie*
 Title    High Activity of Binuclear Cobalt(II) Complex for Ethylene Evolution from 1-AminocycIopropane-l-carboxylic Acid in the Presence of Hydrogen Peroxide  
 Abstract    The binuclear C o(II) and M n(II) complexes with H5(H XTA). where H5(H X TA) repre­ sents N,N'-(2-hydroxy-5-methyl-l,3-xylylene)bis(N-carboxymethylglycine), induced a strong ethylene evolution from 1-aminocyclopropane-l-carboxylic acid (ACC) in the presence of hydrogen peroxide, whereas activities of the corresponding Fe(III), N i(II), and V (III) com­ plexes were found negligible. Based on spectroscopic results and mass-spectral data it is proposed that a peroxide adduct of binuclear Co(II) (and M n(II)) complex with ^'-coordina­ tion mode interacts with ACC, which is chelated to a binuclear cobalt complex leading to facile oxidative degradation of ACC and to evolution of ethylene. 
  Reference    Z. Naturforsch. 54c, 534—541 (1999); received February 25/March 31 1999 
  Published    1999 
  Keywords    Ethylene Evolution, Binuclear Metal Complex, ACC, Hydrogen Peroxide 
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 TEI-XML for    default:Reihe_C/54/ZNC-1999-54c-0534.pdf 
 Identifier    ZNC-1999-54c-0534 
 Volume    54