Go toArchive
Browse byFacets
Bookbag ( 0 )
'Epimerization' in keywords Facet   Publication Year 1978  [X]
Facet   section ZfN Section B  [X]
Results  1 Item
Sorted by   
Publication Year
1Author    Henri Brunner, Manfred MuschiolRequires cookie*
 Title    Optisch aktive Übergangsmetall-Komplexe  
 Abstract    , LV [1]. Darstellung und Stereochemie von [C5H5Mo(CO)2 NN'jPFe mit NTS'=Ethylen-diamin und Propylendiamin Optically Active Transition Metal Complexes, LV [1] Preparation und Stereochemistry of [C5H5Mo(CO)2NN']PF6 with NN'=Ethylenediamine and Propylene -diamine In the reaction of CsHsMotCO^Cl with ethylenediamine and propylenediamine, ab-breviated with NN', the square pyramidal cations [C5H5Mo(C0)2NN'] + are formed. The diastereoisomeric pairs of enantiomers of the propylenediamine derivative are separated by fractional crystallization. The epimerization at the asymmetric Mo atom (n,2 = 30 min, 75 °C, CD3OD solution) can be followed by NMR spectroscopy. 
  Reference    Z. Naturforsch. 33b, 247—248 (1978); eingegangen am 12. Oktober 1977 
  Published    1978 
  Keywords    Diastereoisomeric Pairs of Enantiomers, Separation, Epimerization 
  Similar Items    Find
 TEI-XML for    default:Reihe_B/33/ZNB-1978-33b-0247_n.pdf 
 Identifier    ZNB-1978-33b-0247_n 
 Volume    33