| | 1 | Author
| Henri Brunner, Manfred Muschiol | Requires cookie* | | | Title
| Optisch aktive Übergangsmetall-Komplexe  | | | | Abstract
| , LV [1]. Darstellung und Stereochemie von [C5H5Mo(CO)2 NN'jPFe mit NTS'=Ethylen-diamin und Propylendiamin Optically Active Transition Metal Complexes, LV [1] Preparation und Stereochemistry of [C5H5Mo(CO)2NN']PF6 with NN'=Ethylenediamine and Propylene -diamine In the reaction of CsHsMotCO^Cl with ethylenediamine and propylenediamine, ab-breviated with NN', the square pyramidal cations [C5H5Mo(C0)2NN'] + are formed. The diastereoisomeric pairs of enantiomers of the propylenediamine derivative are separated by fractional crystallization. The epimerization at the asymmetric Mo atom (n,2 = 30 min, 75 °C, CD3OD solution) can be followed by NMR spectroscopy. | | | |
Reference
| Z. Naturforsch. 33b, 247—248 (1978); eingegangen am 12. Oktober 1977 | | | |
Published
| 1978 | | | |
Keywords
| Diastereoisomeric Pairs of Enantiomers, Separation, Epimerization | | | |
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| ZNB-1978-33b-0247_n | | | | Volume
| 33 | |
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