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'Electroreduction' in keywords Facet   Publication Year 1985  [X]
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1985[X]
1Author    Leopold Horner, Christoph Franz, MatthiasRequires cookie*
 Title    Studien zum Vorgang der Wasserstoffübertragung, 76 [1] Der anomale Verlauf der Elektroreduktion von Cumarin mit Lithium als Leitsalzkation Versuche zur Reaktionslenkung durch Mediatoren Studies on the Occurrence of Hydrogen Transfer, 76 [1] The Anomal Course of the Electroreduction of Coumarine with Supporting Electrolyts Containing Li + Experiments to Influence the Reaction by Mediators  
 Abstract    In contradiction to the experience the hydrodimer is formed as the main product in the elec-troreduction of coumarine using lithium compounds as a supporting electrolyt. It is assumed that the lithium ions are coordinated internally with the radicalanion A resp. B derived from coumarine. In this way the hydrodimerization is favoured. From 18 different compounds added as possible mediators to the catholyt only pyridine influences moderately the ratio: hydro-dimerizationproduct/dihydroproduct. 
  Reference    Z. Naturforsch. 40b, 822—825 (1985); eingegangen am 6. Februar 1985 
  Published    1985 
  Keywords    Hydrogen Transfer, Coumarine, Electroreduction 
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 TEI-XML for    default:Reihe_B/40/ZNB-1985-40b-0822.pdf 
 Identifier    ZNB-1985-40b-0822 
 Volume    40