| | 1 | Author
| A.Ntoni Keller, Ludmila Szterenberg | Requires cookie* | | | Title
| Dinitrosylmolybdenum Complexes with Anion Ligands Coordinating by Oxygen Atoms. Synthesis, Electronic Structure and Olefin Metathesis Activity of Carboxylato-Dinitrosyl-Molybdenum Complexes  | | | | Abstract
| The new carboxylato-dinitrosyl-molybdenum complexes o f the formula: [M o(N O)2(0 2CMe)2] • M eOH , N a2[M o(N O)2(0 2CM e)4] and M o(N O)2(0 2CPh)2 have been synthesized. Their structure was resolved on the basis o f spectroscopic investigations ('H N M R , IR, U V -V IS). Catalytic activity o f these complexes in olefin metathesis reaction was also examined. The electronic structure o f dinitrosyl-molybdenum complexes with ligands coordinating by oxygen atom s was calculated for the example o f the di-and tetra-acetato-dinitrosyl-molybden-um com plexes using the Fenske-Hall and IN D O methods. To interpret the spectroscopic properties (U V -V IS) within the method o f interaction configuration, the electronic structure o f the excited states was calculated. | | | |
Reference
| Z. Naturforsch. 47b, 1469—1476 (1992); received December 13 1991 | | | |
Published
| 1992 | | | |
Keywords
| D initrosylm olybdenum Complexes, Carboxylato Complexes, Electronic Structure Calculation, Spectroscopic Properties, Olefin M etathesis | | | |
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| default:Reihe_B/47/ZNB-1992-47b-1469.pdf | | | | Identifier
| ZNB-1992-47b-1469 | | | | Volume
| 47 | |
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