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1996[X]
1Author    H. Kunkely, A. VoglerRequires cookie*
 Title    Photoredox Decomposition of [Cobalamin-^-NC-Fen(CN)5]3* Induced by Metal-to-Metal Charge Transfer Excitation  
 Abstract    In the presence of oxygen aqueous solutions of the binuclear complex [cobalamin-^-NC-Fe(C N)5]3' undergo a redox photolysis (0 ~ 2 x 10'3 at Airr = 405 nm) which yields aquocoba-lamin and [Fe(C N)6]3\ It is suggested that this photoreaction is induced by direct metal-to-metal charge transfer (M M CT) excitation. On the contrary, [cobalamin-fx-NC-Ru(CN)5]3' is photo-inert because a reactive MMCT state is not accessible. 
  Reference    Z. Naturforsch. 51b, 245 (1996); received July 7 1995 
  Published    1996 
  Keywords    Vitamin B I2, Photolysis, Electron Transfer, Cyano Complexes, Iron 
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 TEI-XML for    default:Reihe_B/51/ZNB-1996-51b-0245.pdf 
 Identifier    ZNB-1996-51b-0245 
 Volume    51