| | 3 | Author
| Joseph Grobe, Heinz Zimmermann | Requires cookie* | | | Title
| Elektrochemische Synthesen, VI [1]  | | | | Abstract
| Elektrochemische Substitution der YIB-Hexacarbonyle M(CO)6 (M = Cr, Mo, W) Electrochemical Syntheses, VI [1] Electrochemical Substitution of VIB-Hexacarbonyls M(CO)6 (M = Cr, Mo, W) The electrochemical substitution of group VIB hexacarbonyls by solvent molecules and/or phosphane ligands is studied in some detail and is found to be a fruitful alternative preparative route to the well-known photochemical reaction. | | | |
Reference
| Z. Naturforsch. 36b, 301—306 (1981); eingegangen am 24. Oktober 1980 | | | |
Published
| 1981 | | | |
Keywords
| Electrochemical Synthesis, Metal Carbonyls, Substitution Products, Phosphane Ligands | | | |
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| | | | | TEI-XML for
| default:Reihe_B/36/ZNB-1981-36b-0301.pdf | | | | Identifier
| ZNB-1981-36b-0301 | | | | Volume
| 36 | |
| 4 | Author
| Joseph Grobe, Heinz Zimmermann, Frau | Requires cookie* | | | Title
| Elektrochemische Synthesen, VII [1] | | | | Abstract
| Elektrochemische Substitutionsreaktionen an M(CO)6_n(PR3)M-Komplexen (M = Cr, Mo, W) Electrochemical Syntheses, VII [1] Electrochemical Substitution Reactions of M(CO)6-n(PR3)n Complexes (M = Cr, Mo, W) The principle of electrochemical substitution of metal carbonyls has been applied to monosubstituted derivatives M(CO)5PR3 (M = Cr, Mo, W) with the aim of selective prepa-ration of di-and trisubstituted products M(CO)4(PR3)(PR'3) or M(CO)3(PR3)(PR'3)2. It is shown that, due to simultaneous replacement of CO and PR3 mixtures of products are formed. | | | |
Reference
| Z. Naturforsch. 36b, 482—484 (1981); eingegangen am 24. Oktober 1980 | | | |
Published
| 1981 | | | |
Keywords
| Electrochemical Synthesis, Metal Carbonyl Derivatives, Phosphane Ligands | | | |
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| default:Reihe_B/36/ZNB-1981-36b-0482.pdf | | | | Identifier
| ZNB-1981-36b-0482 | | | | Volume
| 36 | |
| 5 | Author
| T. Sogo, J. Romero, A. Sousa, A. De Blas, M. L. Durán, E. E. Castellano | Requires cookie* | | | Title
| The Electrochemical Synthesis of Neutral Zinc(II) Complexes of Schiff Base Ligands: The Crystal Structure of Bis[N-(4-methylphenyl)salicylaldiminato]zinc(II) | | | | Abstract
| The electrochemical synthesis and physico-chemical properties of neutral zinc(II) complexes of bidentate Schiff bases derived from salicylaldehydes are presented together with the X-ray struc-ture of bis[N-(4-methylphenyl)salicylaldiminato]zinc(II). The crystal is monoclinic, a = 21.877(3), b = 8.801(2), c = 12.027(5) Ä, ß = 96.55(3)°, space group C2/c. The complex is a monomer, and the zinc atom is tetrahedrally coordinated. | | | |
Reference
| Z. Naturforsch. 43b, 611—615 (1988); received November 5 1987/January 28. 1988 | | | |
Published
| 1988 | | | |
Keywords
| X-Ray, Zinc, Schiff Bases, Electrochemical Synthesis | | | |
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| default:Reihe_B/43/ZNB-1988-43b-0611.pdf | | | | Identifier
| ZNB-1988-43b-0611 | | | | Volume
| 43 | |
| 6 | Author
| R. Castro, M.L D Urán, J.A G Arcía-Vázquez, J. Romero, A. Sousa, A. Castiñeiras, W. Hiller, J. Strähle | Requires cookie* | | | Title
| Electrochemical Syntheses of Pyrimidine-2-thiolato Complexes of Nickel(II) Crystal and Molecular Structure of 2,2 -Bipyridine-bis(pyrimidine-2-thiolato)nickel(II) Monohydrate+ | | | | Abstract
| The electrochemical oxidation o f nickel in pyrimidine-2-thione (pym tH) solution yields a com pound o f formula [Ni(pymt)-,]. When pyridine (py), 2,2'-bipyridine (bipy) or 1,10-phenan throline (phen) are added to the solution phase, the product obtained is a complex [Ni(pym t)2py2] or [Ni(pym t)2L] (L = bipy or phen). The crystal structure o f [Ni(pym t)2bipy] • H 20 is monoclinic, space group P 2,/c, with a = 726.6(2), b = 1586.2(2), c = | | | |
Reference
| Z. Naturforsch. 45b, 1632—2 (1990); received May 14 1990 | | | |
Published
| 1990 | | | |
Keywords
| Crystal Structure, Nickel(II) Complexes, Pyrimidine-2-thione, Electrochemical Syntheses | | | |
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| default:Reihe_B/45/ZNB-1990-45b-1632.pdf | | | | Identifier
| ZNB-1990-45b-1632 | | | | Volume
| 45 | |
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