| | 2 | Author
| Joseph Grobe, Heinz Zimmermann | Requires cookie* | | | Title
| Elektrochemische Synthesen, VI [1]  | | | | Abstract
| Elektrochemische Substitution der YIB-Hexacarbonyle M(CO)6 (M = Cr, Mo, W) Electrochemical Syntheses, VI [1] Electrochemical Substitution of VIB-Hexacarbonyls M(CO)6 (M = Cr, Mo, W) The electrochemical substitution of group VIB hexacarbonyls by solvent molecules and/or phosphane ligands is studied in some detail and is found to be a fruitful alternative preparative route to the well-known photochemical reaction. | | | |
Reference
| Z. Naturforsch. 36b, 301—306 (1981); eingegangen am 24. Oktober 1980 | | | |
Published
| 1981 | | | |
Keywords
| Electrochemical Synthesis, Metal Carbonyls, Substitution Products, Phosphane Ligands | | | |
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| | | | | TEI-XML for
| default:Reihe_B/36/ZNB-1981-36b-0301.pdf | | | | Identifier
| ZNB-1981-36b-0301 | | | | Volume
| 36 | |
| 3 | Author
| Joseph Grobe, Heinz Zimmermann, Frau | Requires cookie* | | | Title
| Elektrochemische Synthesen, VII [1] | | | | Abstract
| Elektrochemische Substitutionsreaktionen an M(CO)6_n(PR3)M-Komplexen (M = Cr, Mo, W) Electrochemical Syntheses, VII [1] Electrochemical Substitution Reactions of M(CO)6-n(PR3)n Complexes (M = Cr, Mo, W) The principle of electrochemical substitution of metal carbonyls has been applied to monosubstituted derivatives M(CO)5PR3 (M = Cr, Mo, W) with the aim of selective prepa-ration of di-and trisubstituted products M(CO)4(PR3)(PR'3) or M(CO)3(PR3)(PR'3)2. It is shown that, due to simultaneous replacement of CO and PR3 mixtures of products are formed. | | | |
Reference
| Z. Naturforsch. 36b, 482—484 (1981); eingegangen am 24. Oktober 1980 | | | |
Published
| 1981 | | | |
Keywords
| Electrochemical Synthesis, Metal Carbonyl Derivatives, Phosphane Ligands | | | |
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| default:Reihe_B/36/ZNB-1981-36b-0482.pdf | | | | Identifier
| ZNB-1981-36b-0482 | | | | Volume
| 36 | |
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