| | 1 | Author
| H. S. Sangari, G. S. Sodhi, N. K. Kaushik, R. P. Singh | Requires cookie* | | | Title
| Bis(?? 5 -cyclopentacüenyl)N,N-Disiibstituted Dithiocarbamato(cUoro)oxomolybdeniim(VI) Complexes  | | | | Abstract
| Bis(?j 5 -cyclopentadienyl)N,N-disubstituted Dithiocarbamato(chloro)oxomolybdenum(VI) complexes of the type (C5H5)2MoO(S2CNR2)C1 and (CsHshMoO^CNRR'JCl where R = Me, Et, «'-Pr and R' = cyclohexyl (cyhx) have been prepared by the reaction of stoichio- metric amounts of bis(^5-cyclopentadienyl)oxomolybdenum(VI) dichloride with sodium dichio-thiocarbamates in refluxing dichloromethane. Infrared spectral studies demonstrate that in these complexes, the dithiocarbamate ligands are bidentate. Hence a coordination number of 7 may be assigned to the molybdenum(VI) atom in each case. In addition to infrared studies, electronic spectra, NMR studies, magnetic susceptibility, elemental analyses and conductance measurements have been carried out for these complexes. | | | |
Reference
| Z. Naturforsch. 35b, 1254—1256 (1980); received May 9 1980 | | | |
Published
| 1980 | | | |
Keywords
| Complexes, Electrical Conductance, Magnetic Susceptibility, Electronic Spectra, NMR Spectra | | | |
Similar Items
| Find | | | DEBUG INFO
| | | | | TEI-XML for
| default:Reihe_B/35/ZNB-1980-35b-1254.pdf | | | | Identifier
| ZNB-1980-35b-1254 | | | | Volume
| 35 | |
|
