| | 1 | Author
| Makoto Kaga, Piotr Koziol, Tetsuo Asaji, Daiyu Nakamura | Requires cookie* | | | Title
| Electric field Gradient Modulation by Motion of Lone-Pair Electrons in [(CH 3 ) 3 S] 2 MC1 6 (M = Pt, Sn) as a Possible Relaxation Mechanism of Chlorine Nuclear Quadrupole Resonance  | | | | Abstract
| The temperature dependence of the chlorine NQR spin-lattice relaxation time T^was observed for trimethylsulfonium hexachlorometallates(IV), [(CH 3) 3 S] 2 MC1 6 (M = Pt, Sn), trimethylammonium hexachlorostannate(IV), [(CH 3) 3 NH] 2 SnCl 6 , and tetramethylphosphonium hexachlorostannate(IV), [(CH 3) 4 P] 2 SnCl 6 . The quadrupolar relaxation in [(CH 3) 3 NH] 2 SnCl 6 and [(CH 3) 4 P] 2 SnCl 6 can be described by the usual librational and reorientational motion of the complex anion at lower and higher temperatures, respectively. Besides T 1Q due to these two mechanisms, T 1Q minimum was observed at ca. 90 and 120 K for [(CH 3) 3 S] 2 PtCl 6 and [(CH 3) 3 S] 2 SnCl 6 , respectively, which is attributable to the electric field gradient modulation by the motion of the [(CH 3) 3 S] + cation having lone-pair electrons. The activation energies for the isotropic reorientation of the complex anion were determined as46,65, 59, and 60 kJ mol^ for [(CH 3) 4 P] 2 SnCl 6 , [(CH 3) 3 NH] 2 SnCl 6 , [(CH 3) 3 S] 2 PtCl 6 , and [(CH 3) 3 S] 2 SnCl 6 , respectively. | | | |
Reference
| Z. Naturforsch. 45a, 1033—1037 (1990); received May 26 1990 | | | |
Published
| 1990 | | | |
Keywords
| Nuclear Quadrupole Resonance, Spin-Lattice Relaxation, EFG Modulation, Lone-Pair Electrons | | | |
Similar Items
| Find | | | DEBUG INFO
| | | | | TEI-XML for
| default:Reihe_A/45/ZNA-1990-45a-1033.pdf | | | | Identifier
| ZNA-1990-45a-1033 | | | | Volume
| 45 | |
|
