| | 1 | Author
| Synthesis, Crystal Structure Of, HerbertW. Roesky, Hartmut Hofmann, Mathias Noltemeyer, GeorgeM. Sheldrick | Requires cookie* | | | Title
| Synthese und Kristallstruktur von l,l,l,3,3»3-Hexafluor-2-propylamino- l-thiooxamid +-Hexafluoro-2-propylamino- 1-thiooxamide"  | | | | Abstract
| Dithiooxamide 1 reacts with hexafluoroacetone 2 at room temperature to yield 1,1,1,3,3,3-hexafluoro-2-propylamino-l-thiooxamide 3 and sulfur. The modes of formation of the bis(trifluoromethyl)-methyl group from hexafluoroacetone, the migra-tion of oxygen and the elimination of sulfur are not clear. Crystals of 3 are monoclinic, space group Cc, with a = 2865.3(13), b = 924.4(9), c = 702.9(6) pm, ß = 93.3(7)°. The structure was re-fined to R — 0.067 from 614 reflections. | | | |
Reference
| (Z. Naturforsch. 40b, 124—126 [1985]; eingegangen am 13. August 1984) | | | |
Published
| 1985 | | | |
Keywords
| Dithiooxamide, Hexafluoroacetone, Crystal Structure | | | |
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| ZNB-1985-40b-0124_n | | | | Volume
| 40 | |
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