Go toArchive
Browse byFacets
Bookbag ( 0 )
'Dithiooxamide' in keywords Facet   section ZfN Section B  [X]
Results  1 Item
Sorted by   
Publication Year
1985 (1)
1Author    Synthesis, Crystal Structure Of, HerbertW. Roesky, Hartmut Hofmann, Mathias Noltemeyer, GeorgeM. SheldrickRequires cookie*
 Title    Synthese und Kristallstruktur von l,l,l,3,3»3-Hexafluor-2-propylamino- l-thiooxamid +-Hexafluoro-2-propylamino- 1-thiooxamide"  
 Abstract    Dithiooxamide 1 reacts with hexafluoroacetone 2 at room temperature to yield 1,1,1,3,3,3-hexafluoro-2-propylamino-l-thiooxamide 3 and sulfur. The modes of formation of the bis(trifluoromethyl)-methyl group from hexafluoroacetone, the migra-tion of oxygen and the elimination of sulfur are not clear. Crystals of 3 are monoclinic, space group Cc, with a = 2865.3(13), b = 924.4(9), c = 702.9(6) pm, ß = 93.3(7)°. The structure was re-fined to R — 0.067 from 614 reflections. 
  Reference    (Z. Naturforsch. 40b, 124—126 [1985]; eingegangen am 13. August 1984) 
  Published    1985 
  Keywords    Dithiooxamide, Hexafluoroacetone, Crystal Structure 
  Similar Items    Find
 TEI-XML for    default:Reihe_B/40/ZNB-1985-40b-0124_n.pdf 
 Identifier    ZNB-1985-40b-0124_n 
 Volume    40