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1Author    U. D. Rutkow Ski, P. StrauchRequires cookie*
 Title    Oxidative S-S-Kopplung von 1,2-Dithiooxalat durch intramolekulare Redoxreaktion der Selen(II)-und Tellur(II)-Komplexe O xidative S-S C oupling o f 1,2-D ithiooxalate by Intramolecular R edox Reaction o f the Selenium (II) and Tellurium (II) C om plexes  
 Abstract    The reaction of sodium monochalcogenopentathionates, Na2[Y(S20 3)2] (Y = Se, Te) with potassiumdithiooxalate in a water/methanol solution in presence of large cations (e. g. Ph4P+, Ph4As+ or BzlPh3P+) yields complexes of the type [Y(dto)2]2~ (Y = Se, Te). These complexes are of limited stability and undergo a redox reaction in solution. As the main product of this redox process the 3,4-dithiahexane-2,5-dione-l,6-di(thiocarboxylate) was isolated and characterized by X-ray structure analysis as the benzyltriphenylphosphonium salt (monoclinic space group P2^/c, Z = 2, a = 8.899(5) A, b = 16.458(2) Ä, c = 16.034(6) A and ß = 98.02(2)°). With Te_+ (Y = Te) as the coordination center we have been able to isolate the intermediate complex (Ph4P)2[Te(dto)2], 
  Reference    (Z. Naturforsch. 54b, 73—76 [1999]; eingegangen am 13. August 1998) 
  Published    1999 
  Keywords    1, 2-Dithiooxalate, X-Ray Data, Disulfide 
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 TEI-XML for    default:Reihe_B/54/ZNB-1999-54b-0073.pdf 
 Identifier    ZNB-1999-54b-0073 
 Volume    54