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1978 (1)
1Author    Cornelia Neidl, Joachim StauffRequires cookie*
 Title    Spectra and Decay Kinetics of Diadamantyl-Dioxetane Chemiluminescence  
 Abstract    The thermal decomposition of 1,2-diadamantyldioxetane was studied by kinetic and spectroscopic methods. Spectra of the chemiluminescence emitted during the thermally induced decomposition of 1,2-diadamantyldioxetane, tetramethyldioxetane and tri-methyldioxetane were obtained and the influence of quenchers and radical-scavengers, and the presence of "heavy atoms" in the surrounding of the emitting species was investigated. The kinetics of the decay mechanism was followed by measuring the time dependence of the chemiluminescence. The influence of radical-scavengers, quenchers and "external heavy atoms" on the kinetics was assessed. Experimental results were discussed in terms of a biradical decay mechanism. 
  Reference    Z. Naturforsch. 33b, 763—769 (1978); received January 26 1978 
  Published    1978 
  Keywords    Chemiluminescence, Dioxetanes, Reaction Kinetics, Spectra, Biradicals 
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 TEI-XML for    default:Reihe_B/33/ZNB-1978-33b-0763.pdf 
 Identifier    ZNB-1978-33b-0763 
 Volume    33