1 | Author | Matthias Moll, Peter Würstl, Helmut Behrens, Peter Merbach | Requires cookie* |
Title | Über neue zweikernige Metallcarbonylkomplexe mit Cyclohexadienyl-cycloheptatrien-und Cyclohexadienyl-isonitril-Brücken On New Dinuclear Metal Carbonyl Complexes with Cyclohexadienyl Cycloheptatriene and Cyclohexadienyl Isonitrile Bridges ![]() | ||
Abstract | The reactions of the electrophilic [C6H7Fe(CO)3] + -and [C6H7Fe(CO)2CNEt]+-cations with theextremely nucleophilic [C7H7Fe(CO)3] _ -anion lead to the formation of the dinuclear cyclohexadienyl cycloheptatriene bridged complexes (OC)3FeC6H7-C7H7Fe(CO)3 and EtNC(OC)2FeCeH7-C7H7Fe(CO)3. In a similar reaction the tricarbonyl cation [CeH7Fe(CO)3] + with [Cr(CO)5CN] _ yields the dinuclear cyclohexadienyl isonitrile bridged compound (OC)3FeC6H7-NCCr(CO)5. The mass, IR and NMR data of the new complexes are reported. | ||
Reference | Z. Naturforsch. 33b, 1304—1308 (1978); eingegangen am 19. Juli 1978 | ||
Published | 1978 | ||
Keywords | Cyclohexadienyl Cycloheptatriene Iron Carbonyl Complexes, Iron Isonitrile Carbonyl Complexes, Dinuclear Cyclohexadienyl Isonitrile Carbonyl Complex, Iron, Chromium | ||
Similar Items | Find |