| | 1 | Author
| M. Enders, R. Rudolph, H. Pritzkow | Requires cookie* | | | Title
| Synthese und Kristallstruktur von Pentakis(dimethylsulfoxid)- oxo-titan(IV)chlorid Synthesis and Crystal Structure o f Pentakis(dimethylsulfoxide)-oxo-titanium(IV) Chloride  | | | | Abstract
| Pentakis(dimethylsulfoxide)-oxo-titanium(IV) chloride is obtained by reaction of titanium tetrachloride with a stoichiometric amount of water in dimethylsulfoxide. A single crystal structure determination (P i, a = 9.564(6), b = 10.504(7), c = 12.510(8) A. a = 70.21(5), ß = 83.48(5), 7 = 89.82(5)°, V = 1174 Ä 3, Z = 2) shows a dicationic titanium(IV) complex with five dimethylsulfoxide ligands and one oxygen atom. The two chlorine anions are not bonded to the complex cation. The T i0 6-fragment is a distorted octahedron, where five of the six oxygen atoms belong to the coordinated dimethylsulfoxide molecules. | | | |
Reference
| Z. Naturforsch. 52b, 496—499 (1997); eingegangen am 23. Dezember 1996 | | | |
Published
| 1997 | | | |
Keywords
| Titanium Oxo Complexes, Dimethylsulfoxide, Crystal Structure | | | |
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| default:Reihe_B/52/ZNB-1997-52b-0496.pdf | | | | Identifier
| ZNB-1997-52b-0496 | | | | Volume
| 52 | |
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