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1997 (1)
1Author    M. Enders, R. Rudolph, H. PritzkowRequires cookie*
 Title    Synthese und Kristallstruktur von Pentakis(dimethylsulfoxid)- oxo-titan(IV)chlorid Synthesis and Crystal Structure o f Pentakis(dimethylsulfoxide)-oxo-titanium(IV) Chloride  
 Abstract    Pentakis(dimethylsulfoxide)-oxo-titanium(IV) chloride is obtained by reaction of titanium tetrachloride with a stoichiometric amount of water in dimethylsulfoxide. A single crystal structure determination (P i, a = 9.564(6), b = 10.504(7), c = 12.510(8) A. a = 70.21(5), ß = 83.48(5), 7 = 89.82(5)°, V = 1174 Ä 3, Z = 2) shows a dicationic titanium(IV) complex with five dimethylsulfoxide ligands and one oxygen atom. The two chlorine anions are not bonded to the complex cation. The T i0 6-fragment is a distorted octahedron, where five of the six oxygen atoms belong to the coordinated dimethylsulfoxide molecules. 
  Reference    Z. Naturforsch. 52b, 496—499 (1997); eingegangen am 23. Dezember 1996 
  Published    1997 
  Keywords    Titanium Oxo Complexes, Dimethylsulfoxide, Crystal Structure 
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 TEI-XML for    default:Reihe_B/52/ZNB-1997-52b-0496.pdf 
 Identifier    ZNB-1997-52b-0496 
 Volume    52