| | 1 | Author
| Gerd-Volker Röschenthaler | Requires cookie* | | | Title
| Über die Reaktionen von Phosphanen MenP [OCH(CF3 )2] 3_" mit Hexafluoraceton Reactions of Phosphanes MenP[OCH(CF3)2]3-n with Hexafluoroacetone  | | | | Abstract
| The stable phosphanes Me2POCH(CF3)2 and MeP[OCH(CF3)2]2 have been prepared and reacted with hexafluoroacetone yielding 1,2-oxaphosphetanes. The analogous reaction with Me2PF was carried out giving a 1 : 1 : 1 mixture of a 1,3,2-, a 1,3,4-dioxaphospholane, and a 1,2-oxaphosphetane. P[OCH(CF3)2]3 did not react with hexafluoroacetone. The new compounds were characterized by NMR, mass spectrometry and elemental analysis. | | | |
Reference
| Z. Naturforsch. 33b, 131—135 (1978); eingegangen am 12. September 1977 | | | |
Published
| 1978 | | | |
Keywords
| Dimethylhexafluoroisopropoxyphosphane, Methyl-bis(hexafluoroisopropoxy)phosphane, 1, 2-Oxaphosphetanes, Oxyphosphoranes, Hexafluoroacetone | | | |
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| default:Reihe_B/33/ZNB-1978-33b-0131.pdf | | | | Identifier
| ZNB-1978-33b-0131 | | | | Volume
| 33 | |
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