| | 1 | Author
| PeterG. Jones, M. Artina, Näveke Und Arm, Blaschette | Requires cookie* | | | Title
| Polysulfonylamine, XXXI [1] Kristallstruktur von (1-Trichlormethylthio- 4-dimethylaminopyridinium)dimesylamid bei -9 5 °C Polysulfonylamines, XXXI [1] Crystal Structure o f 1-Trichloromethylthio- 4-dimethylaminopyridinium Dimesylamide at -9 5 °C  | | | | Abstract
| The crystal structure o f the title com pound was determined at -9 5 °C. It crystallizes in space group P 1 with a = 577.5(3), b = 820.2(3), c = 1916.6(8) pm, a = 83.34(2), ß = 82.83(2), y = 83.61(2)° and Z = 2. The final R value was 0.034 for 3019 unique observed reflections. The presence o f aggregates o f four ions (two cations and two an ions) in the solid state is observed, with short cat-ion-anion contacts Sn — 0 (290 pm) and Cl --O (298 pm). The bond lengths o f the 4-dimethyl-aminopyridinium moiety o f the cation suggest a semiquinoid resonance form with a double bond to the nitrogen o f the dim ethylam ino group and two localized double bonds in the ring. The ring, the dimethylamino group (except H atom s) and the Sn atom are coplanar. The S " -N bond length is 170.3 pm, the N -S " -C angle 99.6°. The S ° -C bond is approximately perpendicular to the ring plane. | | | |
Reference
| Z. Naturforsch. 47b, 441—4 (1992); eingegangen am 17. September 1991 | | | |
Published
| 1992 | | | |
Keywords
| Pyridinium, Dimesylamide, Polysulfonylamine, X-Ray | | | |
Similar Items
| Find | | | DEBUG INFO
| | | | | TEI-XML for
| default:Reihe_B/47/ZNB-1992-47b-0441_n.pdf | | | | Identifier
| ZNB-1992-47b-0441_n | | | | Volume
| 47 | |
| 2 | Author
| Karna Wijaya, Oliver Moers, Blaschette Arm, PeterG. Jones | Requires cookie* | | | Title
| Polysulfonylamine, CXII [1] Neues aus der Festkörperchemie der 2-Pyridone: Isolierung und Röntgenstrukturen von Bis(2-pyridon)hydrogen(I)-und Bis(6-methyl-2-pyridon)hydrogen(I)-dimesylamid Polysulfonylamines, CXII [1] A Novel Solid-State Aspect of 2-Pyridones: Isolation and X-Ray Structures of Bis(2-pyridone)hydrogen(I) and Bis(6-methyl-2-pyridone)hydrogen(I) Dimesylamides | | | | Abstract
| The compounds (2-pyridone)2H +(M e S 0 2)2N~ (1, monoclinic, space group V ljn) and ( | | | |
Reference
| Z. Naturforsch. 54b, 643 (1999); eingegangen am 11. Januar 1999 | | | |
Published
| 1999 | | | |
Keywords
| 2-Pyridones, 2-Hydroxypyridines, Dimesylamide, Hom oconjugate Cations, Crystal Structure | | | |
Similar Items
| Find | | | DEBUG INFO
| | | | | TEI-XML for
| default:Reihe_B/54/ZNB-1999-54b-0643.pdf | | | | Identifier
| ZNB-1999-54b-0643 | | | | Volume
| 54 | |
|
