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'Dimerization of Dimethylbutadiene' in keywords
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1980 (1)
1Author    Friedrich-Wilhelm Grevels, Konrad Schneider, Carl Krüger, Richard GoddardRequires cookie*
 Title    Tricarbonyl(^ 4 -1.5-cümethylen-2.6-cümethylcyclooctan)eisen: photochemische Synthese und Struktur Tricarbonyl(^ 4 -l,5-dimethylene-2,6-dimethylcyclooctane)iron: Photochemical Synthesis and Structure  
 Abstract    Extended photolysis of pentacarbonyliron in neat 2,3-dimethylbutadiene results in dimerization of the diene and formation of tricarbonyl(?y 4 -l,5-dimethylene-2,6-dimethyl-cyclooctane)iron (1). The structure of complex 1 is characterized by a trigonal-bipyramidal geometry whereby the exocyclic double bonds of the diene ligand and one of the carbonyl groups lie exactly in the equatorial coordination plane. 
  Reference    Z. Naturforsch. 35b, 360—365 (1980); eingegangen am 5. November 1979 
  Published    1980 
  Keywords    Carbonyliron Olefin Complexes, Dimerization of Dimethylbutadiene, Photochemistry, NMR, X-ray 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-0360.pdf 
 Identifier    ZNB-1980-35b-0360 
 Volume    35