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'Diiodocuprates I' in keywords Facet   section ZfN Section B  [X]
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1983 (1)
1Author    Hans Hartl, Irene Brüdgam, Farbod Mahdjour-Hassan-AbadiRequires cookie*
 Title    Synthese und Strukturuntersuchungen von Iodocupraten(I): II. Diiodocuprate(I) RCuI2 mit isoherten Ketten ^ [Cul4 2~] * R 1 = N-Methylpyridinium, R 2 = Dimethyl ( 3 -dimethylamino -2 -aza -2 -propenyliden ) ammonium [1] Syntheses and Structure Analyses of Iodocuprates(I): II. Diiodocuprates(I) RCUL2 with Isolated Chains [CULI/2~]; R 1 = N-Methylpyridinium, R 2 = Dimethyl(3-dimethylamino-2-aza-2-propenyliden) Ammonium  
 Abstract    N-Methylpyridinium-diiodocuprate(I), CßHgNCuI^ and dimethyl(3-dimethylamino-2-aza-2-propenyliden)ammonium-diiodocuprate(I), C6H14N3CUI2, are obtained by reacting Cu with C6H8NI3 or C6H14N3I3 in acetone. Both compounds are built up by the organic cations and chains of edge sharing tetrahedra<jo[Cul4/2-]. The iodocuprate(I) anions are in intimate contact with the cations via intermolecular I • • • C interactions. Though nearly the same average Cu-I distance of 267.2 or 268.2 pm was found for both iodocuprate(I) anions there are different Cu-Cu distances (301-354 pm). 
  Reference    (Z. Naturforsch. 38b, 57—61 [1983]; eingegangen am 30. September 1982) 
  Published    1983 
  Keywords    Diiodocuprates(I), Synthesis, Crystal Structure 
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 TEI-XML for    default:Reihe_B/38/ZNB-1983-38b-0057.pdf 
 Identifier    ZNB-1983-38b-0057 
 Volume    38