| 1 | Author
| R. Jakubas, G. Bator, M. Foulon, J. Lefebvre, J. Matuszewski | Requires cookie* | | Title
| Structural Phase Transitions in (/i-C 3 H 7 NH3) 2 SbBr 5  | | | Abstract
| Dielectric, DSC, thermal expansion and preliminary X-ray diffraction studies on (/i-C 3 H 7 NH3) 2 SbBr 5 are reported. It was found that this crystal undergoes a complex sequence of phase transitions. On cooling: phase I phase II at 188.7 K (continuous), II -» • III at 165 K (1st order, z!S = 26.8 J/mol K), III IV at 137 K (1st order, 1.6 J/mol K). On heating: IV III at 154 K, III II' at 168 K, II' -> II at 177 K (1st order, 2.8 J/mol K), II I at 189 K. All 1st order phase transitions are likely due to the motion of the n-C 3 H 7 NH3 cations. The dielectric dispersion studies between 100 Hz-1 MHz within the phases I and II indicate a fast reorientational motion of dipoles with T < 10" 7 s. | | |
Reference
| Z. Naturforsch. 48a, 529—534 (1993); received October 7 1992 | | |
Published
| 1993 | | |
Keywords
| Alkylammonium halogenoantimonates, Phase transition, Dielectric, DSC, Thermal expansion | | |
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| default:Reihe_A/48/ZNA-1993-48a-0529.pdf | | | Identifier
| ZNA-1993-48a-0529 | | | Volume
| 48 | |
5 | Author
| Phineus Markwick, Stanislaw Urban, Albert Würflinger | Requires cookie* | | Title
| High Pressure Dielectric Studies of 8CB in the Isotropic, Nematic, and Smectic A Phases  | | | Abstract
| The static and complex permittivity of 4-n-octyl-4'-cyanobiphenyl (8CB) has been measured for the isotropic, nematic and smectic A phases as functions of temperature and pressure. The ranges of 297 -361 K, 0.1 -220 MPa, and 0.1 -13 MHz, were covered. Only the parallel component of the complex permittivity, £*(/) = e'(f) — ie"(f), was measured. The relaxation times T||(p, T) as well as ris(p, T) were analysed at constant temperature, pressure and volumes yielding the activation volume, A ¥ V(T), activation enthalpy A^H(p), and activation energy lyU(V), respectively. All activation parameters calculated for the smectic A phase of 8CB are smaller than those obtained for the nematic phase. The activation energy constitutes approximately half of the activation enthalpy value in all three phases studied. The pressure study allowed to calculate the pressure dependence of the retardation factor g\\(p, T), from which the nematic potential q(p,T) can be derived. Using the relationships between g\\ and q/RT proposed by Kalmykov and Coffey, the order parameter (Piip, T)) was calculated as a function of pressure. | | |
Reference
| Z. Naturforsch. 54a, 275—280 (1999); received March 13 1999 | | |
Published
| 1999 | | |
Keywords
| Liquid Crystals, 8CB, High Pressure, Dielectric, Thermodynamics, Order Parameter | | |
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| default:Reihe_A/54/ZNA-1999-54a-0275.pdf | | | Identifier
| ZNA-1999-54a-0275 | | | Volume
| 54 | |
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