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1979 (1)
1Author    Salvatore SorrisoRequires cookie*
 Abstract    The electric dipole moments of acetyldiazomethane (MeCOCHN2) and 1-acetyl-1-diazo-ethane (MeCOCMeN2) between 10 and 70 °C have been measured. Using appropriate group and bond moments, the concentrations of the two rotamers present in each have been calculated and, hence, the equilibrium constant for the cis trans equilibrium at the various temperatures. ^ The change in standard enthalpy (A H°), standard free energy (A G°) and standard entropy (A S°) are reported for the conversion of one mole of cis isomer to trans isomer. 
  Reference    Z. Naturforsch. 34b, 1530—1534 (1979); received May 17 1979 
  Published    1979 
  Keywords    Dipole Moments, Diazoketones, Thermodynamic, Dielectric Measurements 
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 TEI-XML for    default:Reihe_B/34/ZNB-1979-34b-1530.pdf 
 Identifier    ZNB-1979-34b-1530 
 Volume    34