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'Dielectric Dispersion' in keywords Facet   Publication Year 1998  [X]
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1998[X]
1Author    Masao Hashimoto, Yuko Monobe, Hiromitsu Terao, Haruo Niki, Koichi ManoRequires cookie*
 Title    Phase Transition and Crystal Dynamics of 4-Bromobenzyl Alcohol  
 Abstract    For the title compound a phase transition from Phase II to Phase I (low and room temperature phases, respectively) was found at ca. 217 K. The temperature dependence of the 8 'Br NQR frequency and that of the dielectric constant showed anomalies at ca. 195 K that were tentatively attributed to a higher order phase transition. A similar anomaly was found at ca. 218 K for 4-chlorobenzyl alcohol which showed a II-I transition at 236 K. The dielectric dispersion observed for both compounds at low temperatures indicates an excitation of a molecular motion with the dielectric relaxation rate of ca. 1 kHz. The temperature dependence of the sl Br NQR frequencies of 2-and 3-bromobenzyl alcohol, measured at T > 77 K, gave no evidence of phase transition in their crystals. 
  Reference    Z. Naturforsch. 53a, 436—441 (1998); received March 24 1998 
  Published    1998 
  Keywords    NQR, Phase Transition, Molecular Motion, Dielectric Dispersion 
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 TEI-XML for    default:Reihe_A/53/ZNA-1998-53a-0436.pdf 
 Identifier    ZNA-1998-53a-0436 
 Volume    53