| 1 | Author | Hans Schäfer | Requires cookie* |
| Title | P-funktionell verbrückte Mangancarbonylkomplexe P-Functionally Bridged Manganese Carbonyl Complexes  | ||
| Abstract | Mn(CO)sBr and (Me3Si)3P react to give Mn2(CO)8 (yuBr) (/UP(SiMe3)2) 3. Using methanol, both Si-P bonds of 3 can be cleaved, forming Mn2(CO)8 (//Br) (//PH2) 4. On dissolving 4 in CCI4 a P-H, C-Cl exchange reaction is observed, yielding Mn2(CO)8 (//Br) (^PC12). IR and NMR data are reported. Bei Untersuchungen über die Ligandeigenschaf-ten der Bis (trimethylsilyl)-Gruppe wurden | ||
| Reference | Z. Naturforsch. 33b, 351—352 (1978); eingegangen am 12. Dezember 1977 | ||
| Published | 1978 | ||
| Keywords | Phosphido, Dichlorophosphido, Bis(trimethyl-silyl)phosphido Bridged Manganese Carbonyls, Phosphorus Bridge Substitution Reactions | ||
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