| | 1 | Author
| ThomasG. Meyer, PeterG. Jones, Reinhard Schmutzler | Requires cookie* | | | Title
| Darstellung neuer Monofluorphosphine und einiger ihrer Übergangsmetallkomplexe; Einkristall-Röntgenstrukturanalyse eines Platin(II)-Komplexes Preparation of New M onofluorophosphines and Some o f their Transition Metal Complexes; Single Crystal X-Ray Diffraction Study o f a Platinum (II) Complex  | | | | Abstract
| The reaction of lithiated precursors with PC12F led to a num ber of monofluorophosphines, including the known di-/e>7-butylmonofluorophosphine, 1. Bis(phenylethinyl)monofluoro-phosphine (2) was accessible only via this route (the classical method of synthesizing 2 by chlorine/fluorine exchange is impossible, because the corresponding chlorophosphine is un known). Bis(2-methoxyphenyl)fluorophosphine (5) was prepared via the organolithium /PCl2F route. The N M R results for 5 thus prepared were inconsistent with previous reports, implying that the previously reported synthesis o f 5 is in error. From 5 a m -dichloroplatinum (II) com plex (6) was synthesized and subjected to a single crystal X-ray structure analysis, confirming the expected planar coordination. From bis(2,3-dimethoxynaphthyl)monofluoro-phosphine (7) a rhodium(I) (8) and an iron(0)tetracarbonyl complex (9) were prepared. An iron(0)tetracarbonyl complex (11) was synthesized from bis(9-anthryl)monofluorophosphine (10) which was found to be stable to redox disproportionation. | | | |
Reference
| Z. Naturforsch. 48b, 875—885 (1993); eingegangen am 16. Februar 1993 | | | |
Published
| 1993 | | | |
Keywords
| Dichlorofluorophosphine, M onofluorophosphines, Transition Metal Complexes, X-Ray | | | |
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| 48 | |
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